Proses Pembuatan Biofuel dengan Metode perengakahan Menggunakan Katalis Padat

Agus Budianto, Ayuni Rita Sari, Yohana Winda Monica, Erlinda Ningsih, Esthi Kusdarini

Abstract

The development of population growth causes of fuels need increasing. Because of
that reason, it necessary to create alternative fuels which are friendly to the
environment to meet the fuels need in society. Fossil fuel is a non-renewable fuel.
Biofuel as an alternative fuel can be taken as a solution to solve this problem. The
reviewd aim was to determine the effect of raw materials used on yield product and
the different effects of temperature and catalysts on the yield of special materials
(gasoline, diesel, kerosene) biofuel. Biofuel production started from the
preparation of raw materials, catalylic, and catalytic cracking process using a
fixed bed reactor. Raw materials greatly affected yield product. The highest yield
products were being gotten from RBDPS raw materials of 93.29%. Biofuel from
used cooking oil and concentration of red sludge catalyst of 15% produced the
highest biofuel with gasoline compound of 73.86% and kerosene compound of
26.14%. Biofuel from camelina oil with ZSM-5-Zn catalyst concentration of 30%
produced the highest gasoline yield of 75.65%.

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References

Annex, “Pengaruh Suhu Aktivasi Terhadap Daya Serap Karbon Aktif Kulit Kemiri,”

vol. V, pp. SNF2016-MPS-135-SNF2016-MPS-140, 2017, doi:

21009/0305020226.

A. Budianto, D. H. Prajitno, A. Roesyadi, and K. Budhikarjono, “HZSM-5

CATALYST FOR CRACKING PALM OIL TO BIODIESEL : A COMPARATIVE

STUDY WITH AND,” vol. 15, no. 1, pp. 81–90, 2014.

A. Budianto, D. S. Hajj, and D. A. Rp, “Pembuatan Biofuel dengan Proses

Perengkahan dari Palm Fatty Acid Distillate ( PFAD ) Menggunakan Katalis CaO,”

pp. 607–614, 2019.

R. Tambun, R. P. Saptawaldi, M. A. Nasution, and N. Oktris, “Pembuatan Biofuel

dari Palm Stearin dengan Proses Perengkahan Katalitik menggunakan Katalis ZSM-

Catalytic Cracking Process to Product Biofuel from Palm Stearin by using

Catalyst ZSM-5,” vol. 11, no. 1, pp. 46–52, 2016.

A. Budianto, S. Sumari, W. S. Pambudi, and N. Andriani, “Uji Coba Produksi

Biofuel dari RBD Stearin dalam Reaktor Fixed Bed dengan Metode Cracking,”

Pros. Semin. Nas. Sains dan Teknol. Terap., pp. 735–740, 2019.

W. Pangestu, Yelmida, and Zultinar, “Perengkahan Katalitik Palm Fatty Acid

Distillate Menjadi Biofuel Menggunakan Katalis Fly Ash Sawit,” vol. 2, no. 1, pp.

–5, 2015.

M. A.Yusron, Yelmida, and Zultinar, “Perengkahan Katalitik Palm Fatty Acid

Distillate Menjadi Biofuel Menggunakan Katalis Natrium Karbonat dengan Variasi

Temperatur dan Konsentrasi Katalis Natrium Karbonat,” vol. 2, no. 2, pp. 1–6,

N. Nazarudin and U. Jambi, “KONVERSI CRUDE PALM OIL ( CPO ) MENJADI

BIOFUEL DENGAN PERENGKAHAN KATALITIK MENGGUNAKAN

KATALIS Cr-ZEOLIT ALAM,” no. March, 2018.

A. A. Mancio et al., “Thermal catalytic cracking of crude palm oil at pilot scale:

Effect of the percentage of Na2CO3 on the quality of biofuels,” Ind. Crops Prod.,

vol. 91, pp. 32–43, 2016, doi: 10.1016/j.indcrop.2016.06.033.

I. Istadi et al., “Effects of ion exchange process on catalyst activity and plasmaassisted reactor toward cracking of palm oil into biofuels,” Bull. Chem. React. Eng.

& Catal., vol. 14, no. 2, pp. 459–467, 2019, doi:

9767/bcrec.14.2.4257.459-467.

M. Subsadsana, P. Kham-Or, P. Sangdara, P. Suwannasom, and C. Ruangviriyachai,

“Synthesis and catalytic performance of bimetallic NiMo-and NiW-ZSM-5/MCM-

composites for production of liquid biofuels,” Ranliao Huaxue Xuebao/Journal

Fuel Chem. Technol., vol. 45, no. 7, pp. 805–816, 2017, doi: 10.1016/s1872-

(17)30039-7.

Z. Zheng, J. Wang, Y. Wei, X. Liu, F. Yu, and J. Ji, “Effect of La-Fe/Si-MCM-41

catalysts and CaO additive on catalytic cracking of soybean oil for biofuel with low

aromatics,” J. Anal. Appl. Pyrolysis, vol. 143, no. 18, p. 104693, 2019, doi:

1016/j.jaap.2019.104693.

I. G. Andy, A. Parahita, Y. W. Mirzayanti, I. Gunardi, and A. Roesyadi, “Production

of Biofuel via Catalytic Hydrocracking of Kapuk ( Ceiba pentandra ) Seed Oil with

NiMo / HZSM-5 Catalyst,” vol. 06001, pp. 1–5, 2018.

Y. W. Mirzayanti, P. D H, and R. A, “Catalytic hydrocracking of Kapuk seed oil (

Ceiba pentandra ) to produce biofuel using Zn-Mo supported HZSM-5 catalyst

Catalytic hydrocracking of Kapuk seed oil ( Ceiba pentandra ) to produce biofuel

using Zn-Mo supported HZSM-5 catalyst,” 2017.

A. Budianto, S. Sumari, and K. Udyani, “BIOFUEL PRODUCTION FROM

NYAMPLUNG OIL USING CATALYTIC CRACKING PROCESS WITH ZnHZSM-5 / ? ALUMINA CATALYST,” vol. 10, no. 22, pp. 10317–10323, 2015.

Hartati et al., “Highly selective hierarchical ZSM-5 from kaolin for catalytic

cracking of Calophyllum inophyllum oil to biofuel,” J. Energy Inst., 2020, doi:

1016/j.joei.2020.06.006.

A. M. Rabie, E. A. Mohammed, and N. A. Negm, “Feasibility of modified bentonite

as acidic heterogeneous catalyst in low temperature catalytic cracking process of

biofuel production from nonedible vegetable oils,” J. Mol. Liq., vol. 254, no. 2018,

pp. 260–266, 2018, doi: 10.1016/j.molliq.2018.01.110.

I. Aziz, Y. Kurnianti, N. Saridewi, L. Adhani, and W. Permata, “Utilization of

Coconut Shell as Cr2O3 Catalyst Support for Catalytic Cracking of Jatropha Oil into

Biofuel,” J. Kim. Sains dan Apl., vol. 23, no. 2, pp. 39–45, 2020, doi:

14710/jksa.23.2.39-45.

I. Aziz, L. Adhani, T. Yolanda, and N. Saridewi, “Catalytic cracking of Jatropa

curcas oil using natural zeolite of Lampung as a catalyst,” IOP Conf. Ser. Earth

Environ. Sci., vol. 299, no. 1, pp. 6–13, 2019, doi: 10.1088/1755-

/299/1/012065.

X. Zhao, L. Wei, S. Cheng, and J. Julson, “Optimization of catalytic cracking

process for upgrading camelina oil to hydrocarbon biofuel,” Ind. Crops Prod., vol.

, pp. 516–526, 2015, doi: 10.1016/j.indcrop.2015.09.019.

X. Zhao, L. Wei, S. Cheng, Y. Huang, Y. Yu, and J. Julson, “Catalytic cracking of

camelina oil for hydrocarbon biofuel over ZSM-5-Zn catalyst,” Fuel Process.

Technol., vol. 139, pp. 117–126, 2015, doi: 10.1016/j.fuproc.2015.07.033.

X. Zhao, L. Wei, S. Cheng, Y. Cao, J. Julson, and Z. Gu, “Catalytic cracking of

carinata oil for hydrocarbon biofuel over fresh and regenerated Zn/Na-ZSM-5,”

Appl. Catal. A Gen., vol. 507, pp. 44–55, 2015, doi: 10.1016/j.apcata.2015.09.031.

C. Li et al., “Catalytic cracking of Swida wilsoniana oil for hydrocarbon biofuel

over Cu-modified ZSM-5 zeolite,” Fuel, vol. 218, no. November 2017, pp. 59–66,

, doi: 10.1016/j.fuel.2018.01.026.

Z. D. Yigezu and K. Muthukumar, “Biofuel production by catalytic cracking of

sunflower oil using vanadium pentoxide,” J. Anal. Appl. Pyrolysis, vol. 112, pp.

–347, 2015, doi: 10.1016/j.jaap.2015.01.002.

L. Adhani, R. Masrida, N. P. Angela, and R. R. Nugroho, “Analisis Efektivitas

Katalis Fe / Zeolit Pada Cracking Minyak Jelantah Dalam Pembuatan Biofuel,” vol.

, no. 1, pp. 7–11, 2020.

S. Arita, L. N. Komariah, and O. Alfernando, “The effect of H-USY catalyst in

catalytic cracking of waste cooking oil to produce biofuel,” no. February, 2019, doi:

24845/ijfac.v4.i2.67.

A. R. Ratton Coppos, S. Kahn, and L. E. P. Borges, “Biofuels production by thermal

cracking of soap from brown grease,” Ind. Crops Prod., vol. 112, no. July 2017, pp.

–568, 2018, doi: 10.1016/j.indcrop.2017.12.010.

H. Da Silva Almeida et al., “Production of biofuels by thermal catalytic cracking of

scum from grease traps in pilot scale,” J. Anal. Appl. Pyrolysis, vol. 118, pp. 20–33,

, doi: 10.1016/j.jaap.2015.12.019.

D. K. Sari, A. Sundaryono, and D. Handayani, “LIMBAH CAIR PABRIK

MINYAK KELAPA SAWIT DENGAN KATALIS MoNi / HZ,” vol. 1, pp. 127–

, 2017.

S. Lestari, A. Sundaryono, R. Elvia, and U. Bengkulu, “Preparasi dan Karakterisasi

Katalis Mo-Ni/HZ dengan Metode Impregnasi untuk Cracking Katalitik Minyak

Limbah Cair Pengolahan Kelapa Sawit menjadi Bahan Bakar Nabati 1,2,3,” vol. 3,

no. 1, pp. 91–97, 2019.

A. Sundaryono, D. Handayani, Budiman, and S. Winda, “Perengkahan Katalitik

Metil Ester dari Minyak Limbah Cair Pabrik Minyak Kelapa Sawit dengan Katalis

Cr/Mo/HZA dan Ni/Mo/HZA,” vol. 25, no. 1, pp. 78–84, 2015.

F. M. Wako, A. S. Reshad, M. S. Bhalerao, and V. V. Goud, “Catalytic cracking of

waste cooking oil for biofuel production using zirconium oxide catalyst,” Ind. Crops

Prod., vol. 118, no. March, pp. 282–289, 2018, doi: 10.1016/j.indcrop.2018.03.057.

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